A paper by Philipp has been published in the journal "Advanced Synthesis & Catalysis"
In the article "Water Can Accelerate Homogeneous Gold Catalysis" the influence of water on the rate constant is investigated by several intramolecular gold catalyzed reactions. The kinetic data was collected by GC or 1H NMR spectroscopy.
In recent years, the transformation of organic substrates by gold catalysts has become increasingly important and numerous new gold-catalyzed reaction types and gold catalysts have been developed.
The results show that not only a tolerance but also a reaction-promoting influence of water on gold catalysis can be identified and kinetically quantified. This leads to increased reaction rates and can thus be used to save time and money and achieve a higher yield.
Congratulations to Philipp Stein!